(Diethyl ether){1-[2-(1-methyl-1H-imidazol-2-yl-κN 3)-1,1-diphenylethyl]-(1,2,3,3a,7a-η)-indenyl}lithium(I)
نویسندگان
چکیده
In the title compound, [Li(C(27)H(23)N(2))(C(4)H(10)O)], the Li atom possesses a nearly planar trigonal coordination environment (assuming the cyclo-penta-dienyl ring of the indenyl group occupies one coordination place). The diethyl ether ligand adopts a nearly planar W-type conformation.
منابع مشابه
Trichlorido(tetrahydrofuran){(1,2,3,3a,7a-η)-1-[2-(1-trimethylsilyl-1H-imidazol-2-yl-κN 3)-1-methylpropyl]indenyl}zirconium(IV)
The title compound, [ZrCl(3)(C(19)H(25)N(2)Si)(C(4)H(8)O)], was prepared from bis-(N,N-dimethyl-amido-κN)(2-{2-[(1,2,3,3a,7a-η)-inden-yl]-2-methyl-prop-yl}-1H-imidazolido-κN(1))zirconium(IV) [(C(16)H(16)N(2))Zr(NMe(2))] by reaction with excess Me(3)SiCl in tetra-hydro-furan (THF) at elevated temperature. The crystal studied contained a minor non-merohedral twin contaminant [6.3 (4)%] which was ...
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The compound (μ-3,3',3'',3'''-{[2,5,8,15,18,21-hexa-oxatricyclo-[20.4.0.0(9,14)]hexa-cosa-1(22),9,11,13,23,25-hexa-ene-11,12,24,25-tetra-yl]tetra-kis-(methyl-ene)}tetra-kis-(1-methyl-1H-imidazol-2-yl))bis-[(η(4)-cyclo-octa-1,4-diene)rhodium(I)] bis-(hexa-fluoridophosphate) acetonitrile sesquisolvate dihydrate, [Rh2(C8H12)2(C40H42N8O6)](PF6)2·1.5CH3CN·2H2O, crystallized from acetonitrile under a...
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A series of novel zoledronic acid (ZL) derivatives 1-hydroxy-3-(2-methyl-1H-imidazol-1-yl)propane-1,1-diyldiphosphonic acid (MIPrDP), 1-hydroxy-4-(2-methyl-1H-imidazol-1-yl)butane-1,1-diyldiphosphonic acid (MIBDP), and 1-hydroxy-5-(2-methyl-1H-imidazol-1-yl)pentane-1,1-diyldiphosphonic acid (MIPeDP) were prepared and successfully labeled with Tc in high labeling yields. The in vitro stability a...
متن کاملTrichlorido{2-[2-(η5-cyclopentadienyl)-2-methylpropyl]-1-trimethylsilyl-1H-imidazole-κN 3}titanium(IV) tetrahydrofuran hemisolvate
The title compound, [Ti(C(15)H(23)N(2)Si)Cl(3)]·0.5C(4)H(8)O, has been prepared from {2-[2-(η(5)-cyclo-penta-dien-yl)-2-methyl-prop-yl]-1H-imidazolyl-κN(1)}bis-(N,N-diethyl-amido-κN)titanium(IV), (C(12)H(14)N(2))Ti(NEt(2))(2), by reaction with excess of Me(3)SiCl in tetra-hydro-furan (THF) at 353 K. The crystal structure contains THF as adduct solvent, disordered around a center of inversion. T...
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The title compound, {(C(13)H(22)N(4))[Ag(2)I(4)]}(n), was prepared by reaction of 1,3-bis-(N-ethyl-imidazolium-1-yl)propane iodide with silver (I) oxide. In the 3,3'-diethyl-1,1'-(propane-1,3-di-yl)di(1H-imidazol-3-ium) cation, the dihedral angle between the imidazole rings is 49.3 (1)°. In the [Ag(2)I(4)](2-) anion, each Ag(I) atom is bonded to three iodide anions, the two Ag(I) atoms and two ...
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عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009